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a larger image, please click on thumbnail images below. |
Figure 2. Typical pore size distribution in two different
types of activated carbon.
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ACE is
achieved by introducing granules of activated carbon
into the enclosure.
Activated
carbon can be produced from any organic material. The source
material is first heated in an oxygen free environment, to
prevent burning and to remove any volatile components. The
carbon is then activated by additional heating in a controlled
environment of oxygen and steam.
We can see from the magnified images (figure 1) that the
surface of activated carbon contains a multiplicity of cavern-like
pores. In fact these pores penetrate deep into the material
and there are more than a million-fold range of pore sizes,
from visible cracks to holes of molecular dimensions. Porosity
is what distinguishes activated carbon from other carbon materials,
and gives it amazing versatility.
Intermolecular attractions in these pores result in adsorption
forces. Carbon adsorption forces work like gravity, but on
a molecular scale. The pore size distribution is normally
classified into macropores, mesopores (collectively known
as transport pores) and micropores (figure 2).
It is in the latter - also known as adsorption pores - that
the key process of adsorption takes place.
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There are two forms of adsorption - physical and chemical
adsorption.
Chemical adsorption occurs when molecules form a strong
chemical bond. The process is irreversible - a compound
is formed.
Physical adsorption occurs when molecules are weakly
attracted to each other (van der Waals forces).
Physical adsorption is reversible - desorption
is possible. This is the process by which ACE works.
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When
the loudspeaker cone moves backwards, the air in the box is
compressed slightly. In a conventional loudspeaker this results
in a pressure increase which acts to impede the movement of
the cone. In an ACE system, the pressure increase is smaller
because some of the air molecules are momentarily joined to
the surface of the carbon granules (adsorbed). So the impedance
to motion is significantly reduced. When the cone moves forwards
the air molecules are desorbed by the resulting pressure decrease.
Technically, we can consider this as a reduction of air density.
The acoustic compliance of air in
the loudspeaker cabinet is given by
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CA
= VB / r c2 |
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VB
is the nett enclosure volume |
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P
is the density of air |
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c
is the velocity of sound in air |
Therefore
a reduction in density produces an increase in compliance,
equivalent to enlarging
the enclosure.
This stiffness reduction or Compliance Enhancement can be
as much as four times or more
under optimum conditions. Factors of 1.5 to 3 are readily
achievable in practice. Back
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For
a larger image, please click on thumbnail images below.
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Figure 3. Typical frequency dependence of Compliance
Enhancement Factor.
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Figure 4. Water adsorption isotherms for two different
types of activated carbon
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Effective
Frequency Range
The ACE process is principally effective below about 100Hz
(figure 3). Above this frequency performance deteriorates
because the cycle time becomes too short for adsorption and
desorption fully to take place.
Moisture
There is a strong relationship between the tendency of an
activated carbon to adsorb air and its tendency to adsorb
water vapour. Adsorption of water vapour adversely affects
the Compliance Enhancement because the water molecules block
the pores and prevent air adsorption. Therefore we have two
basic requirements of the carbon - 1) that it is kept as dry
as possible,
and 2) that its water uptake is minimal. The former
is a function of the packaging design and the latter a design
issue for the carbon chemist.
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It is
a fundamental restriction of conventional direct-radiator
loudspeaker system design that enclosure volume, efficiency
and low-frequency extension are interdependent. Small [5]
shows that
Improving
any one of these parameters forces a degradation of one or
more of the others. ACE allows the loudspeaker designer to
break this apparently immutable principle.
There are therefore three possible applications of ACE:
1. Reduce volume, maintain efficiency and extension;
2. Increase extension, maintain volume and efficiency;
3. Increase efficiency, maintain volume and extension (requires
changes to drive unit).
We shall illustrate the use of ACE in the exploitation of
(1) above. Back
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1. H.W.Sullivan,
Loud Speaker, U.S.Patent no. 2,797,766, 1957.
2. J.H.Ott, Enclosure System for Sound Generators, U.S.Patent
no. 4,004,094, 1977.
3. E.J.Czerwinski, Device for increasing the Compliance of
a Speaker Enclosure, U.S.Patent
no. 4,101,736, 1978.
4. R.E.Marrs, Acoustic Energy Systems, U.S.Patent no. 4,450,929,
1984.
5. R.H.Small, Closed-Box Loudspeaker Systems Part 1: Analysis,
J. Audio Eng. Soc. 20 (10), 1972.
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